全文获取类型
收费全文 | 3518篇 |
免费 | 497篇 |
国内免费 | 289篇 |
专业分类
化学 | 1128篇 |
晶体学 | 33篇 |
力学 | 121篇 |
综合类 | 13篇 |
数学 | 963篇 |
物理学 | 2046篇 |
出版年
2023年 | 28篇 |
2022年 | 50篇 |
2021年 | 65篇 |
2020年 | 78篇 |
2019年 | 89篇 |
2018年 | 66篇 |
2017年 | 73篇 |
2016年 | 95篇 |
2015年 | 112篇 |
2014年 | 122篇 |
2013年 | 227篇 |
2012年 | 170篇 |
2011年 | 224篇 |
2010年 | 169篇 |
2009年 | 228篇 |
2008年 | 207篇 |
2007年 | 278篇 |
2006年 | 289篇 |
2005年 | 169篇 |
2004年 | 179篇 |
2003年 | 166篇 |
2002年 | 127篇 |
2001年 | 120篇 |
2000年 | 111篇 |
1999年 | 110篇 |
1998年 | 100篇 |
1997年 | 88篇 |
1996年 | 72篇 |
1995年 | 54篇 |
1994年 | 50篇 |
1993年 | 36篇 |
1992年 | 40篇 |
1991年 | 35篇 |
1990年 | 30篇 |
1989年 | 27篇 |
1988年 | 16篇 |
1987年 | 22篇 |
1986年 | 16篇 |
1985年 | 28篇 |
1984年 | 23篇 |
1983年 | 12篇 |
1982年 | 17篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 13篇 |
1978年 | 14篇 |
1977年 | 15篇 |
1976年 | 10篇 |
1975年 | 6篇 |
1974年 | 6篇 |
排序方式: 共有4304条查询结果,搜索用时 218 毫秒
1.
By using angle resolved photoemission spectroscopy, we investigate the electronic structures of Pt-skin layer of Pt–Co and Pt–Ni alloys with CO molecules on the surface. Measured Fermi surface maps and band dispersions reflect the signatures of chemical bonding between Pt-skin layer and CO molecules. Furthermore, the degree of chemical bonding strength of CO molecules, estimated from the energy shift of the participating bands, is found to be reduced on both Pt bimetallic alloys. Our results show how the surface band structure of Pt bimetallic alloys is modified with molecular orbitals of CO molecules on the surface, revealing the important role of the electronic structure in the determination of chemical properties of bimetallic alloys. 相似文献
2.
A general framework for describing photofission observables of actinides at an average excitation energy below 30 MeV 下载免费PDF全文
Guan-Lin Wang Hao-Yang Lan Xiao-Ming Shi Zhi-Chao Zhu Wen Luo 《中国物理C(英文版)》2022,46(8):084102-084102-14
A reasonable prediction of photofission observables plays a paramount role in understanding the photofission process and guiding various photofission-induced applications, such as short-lived isotope production, nuclear waste disposal, and nuclear safeguards. However, the available experimental data for photofission observables are limited, and the existing models and programs have mainly been developed for neutron-induced fission processes. In this study, a general framework is proposed for characterizing the photofission observables of actinides, including the mass yield distributions (MYD) and isobaric charge distributions (ICD) of fission fragments and the multiplicity and energy distributions of prompt neutrons (np) and prompt γ rays (γp). The framework encompasses various systematic neutron models and empirical models considering the Bohr hypothesis and does not rely on the experimental data as input. These models are then validated individually against experimental data at an average excitation energy below 30 MeV, which shows the reliability and robustness of the general framework. Finally, we employ this framework to predict the characteristics of photofission fragments and the emissions of prompt particles for typical actinides including 232Th, 235, 238U and 240Pu. It is found that the 238U(γ, f) reaction is more suitable for producing neutron-rich nuclei compared to the 232Th(γ, f) reaction. In addition, the average multiplicity number of both np and γp increases with the average excitation energy. 相似文献
3.
A Stable Porphyrin Functionalized Graphite Electrode Used at the Oxygen Evolution Reaction Potential
Gianlorenzo Bussetti Roberto Bernasconi Claudia Filoni Luca Magagnin Alberto Bossi Franco Ciccacci Lamberto Duò 《Electroanalysis》2022,34(7):1227-1236
Many researches have been devoted to rechargeable power generators that can store (but also release) energy. This availability is ensured through (e. g.) the oxygen evolution reaction (OER). However, (i) large values of the overpotentials and (ii) a progressive detriment of the anode (graphite) electrode limit the ultimate device. In view of enhancing the electrode performances, graphite was protected by following different strategies, which oblige to follow precise preparation protocols. Here, we prove that a thin layer of free-base porphyrin molecules is able to protect the underneath graphite electrode from detriment even if many (about 100) electrochemical cycles are performed. 相似文献
4.
5.
6.
为明确冷却塔在水平地震下的内力环向分布特征及内在原因,同时探究不同地震波时程与规范反应谱所得内力差异的原因,以某大型双曲冷却塔为例,在动力特性分析的基础上,通过反应谱方法和时程方法的水平地震响应计算及对比分析,对上述两个问题进行了研究。研究表明:由于仅侧弯振型对水平地震有贡献,而塔筒的侧弯振型和实际响应均表现为整体侧倾并伴随微弱的截面“流动”变形,这也使塔筒各内力的环向分布分别呈现正弦、余弦分布特征;其整体侧倾可类比于悬臂杆结构,塔筒子午向轴力FY、子午向弯矩MY、剪力FXY和扭矩MXY的环向分布可借助悬臂杆侧倾时截面正应力和剪应力分布来解释;而截面“流动”变形则决定了环向轴力FX和环向弯矩MX的环向分布;整体侧移显著而截面变形极小也使FY和FXY的幅值在塔筒中下部明显大于FX;由于冷却塔第1阶侧弯振型在水平地震响应中往往起绝对主导作用,因此可先对所选地震波计算得到其反应谱,对比第1阶侧弯振型周期对应的水平地震影响系数α值,即可初步推断不同时程及规范反应谱方法所得结果的大小关系。 相似文献
7.
XPS and resistive studies on thin films of a copper(II)‐based coordination polymer deposited on functionalized interdigital electrodes 下载免费PDF全文
Michael Günthel Jörg Hübscher Rosemarie Dittrich Edwin Weber Yvonne Joseph Florian Mertens 《Journal of Polymer Science.Polymer Physics》2015,53(5):335-344
A symmetrical 2‐thiopyrimidine based molecule with an expanded π‐electron system is synthesized and used to form a self‐assembled monolayer (SAM) on gold surfaces. Utilizing chemical vapor deposition a monolayer of (3‐mercaptopropyl)triethoxysilane is formed on silicon dioxide substrates. Both of these SAM coated substrates are characterized by X‐ray photoelectron spectroscopy and the growth of a coordination polymer built up from 5,5′‐(ethyne‐1,2‐diyl)bis(2‐hydroxyacetophenone) and copper(II) on dual SAM coated transducers is studied. After the deposition procedure on interdigital electrodes the electrical properties of the polymer are investigated performing resistive measurements. A significant change of the resistance, which depends on the surrounding atmosphere, proves the sensing behavior of the synthesized coordination polymer. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 335–344 相似文献
8.
Solvent‐Dependent Structure of the I3− Ion Derived from Photoelectron Spectroscopy and Ab Initio Molecular Dynamics Simulations 下载免费PDF全文
Dr. Naresh K. Jena Ida Josefsson Dr. Susanna K. Eriksson Prof. Anders Hagfeldt Prof. Hans Siegbahn Prof. Olle Björneholm Prof. Håkan Rensmo Dr. Michael Odelius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):4049-4055
Ab initio molecular dynamics (MD) simulations of the solvation of LiI3 in four different solvents (water, methanol, ethanol, and acetonitrile) are employed to investigate the molecular and electronic structure of the I3? ion in relation to X‐ray photoelectron spectroscopy (XPS). Simulations show that hydrogen‐bond rearrangement in the solvation shell is coupled to intramolecular bond‐length asymmetry in the I3? ion. By a combination of charge analysis and I 4 d core‐level XPS measurements, the mechanism of the solvent‐induced distortions has been studied, and it has been concluded that charge localization mediates intermolecular interactions and intramolecular distortion. The approach involving a synergistic combination of theory and experiment probes the solvent‐dependent structure of the I3? ion, and the geometric structure has been correlated with the electronic structure. 相似文献
9.
Elastic scattering angular distributions and total reaction cross-sections of ~(7,10,11,12)Be projectiles are predicted by the systematic ~9 Be global phenomenological optical model potential for target mass numbers ranging from24 to 209. These predictions provide a detailed analysis by their comparison with the available experimental data.Furthermore, these elastic scattering observables are also predicted for some targets out of the mass number range.The results are in reasonable agreement with the existing experimental data, and they are presented in this study. 相似文献
10.
《Current Applied Physics》2015,15(3):319-325
Pd is one of the metals suitable for inducing low-temperature crystallization in Ge. However, it is not clear how residual Pd atoms are integrated into the Ge lattice. Therefore, time-differential γ–γ perturbed angular correlations (TDPAC) technique using the 100Pd(→100Rh) nuclear probe produced by recoil implantation has been applied to study the hyperfine interactions of this probe in single-crystalline undoped Ge. A Pd-vacancy complex aligned along the <111> crystallographic direction with a unique interaction frequency of 8.4(5) Mrad/s has been identified. This complex was measured to have a maximum relative fraction of about 76(4)% following annealing at 350 °C. Further annealing at higher temperatures reduced this fraction, possibly via dissociation of the complex. Calculations suggest dissociation energy of 1.94(5) eV for the complex. DFT calculations performed in this work are in reasonable good agreement with the experimental values for the electric-field gradient of the defect complex in Ge and Si for comparison. The calculations predict a split-vacancy configuration with the Pd on a bond-centred interstitial site having a nearest-neighbour semi-vacancy on both sides (V-PdBI-V) in Ge and Si. 相似文献